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Statement

Volatile Organic Compounds

Volatile Organic Compounds - VOCs

Technique:
GC/MS Purge and Trap


Reference method:
Derived from US EPA Method 624 (CLP modified) and Method 8260B

Compounds:

624 List

8260 List

Acetone

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Butanone (MEK)

Carbon disulphide

Carbon tetrachloride

Chlorobenzene

Chloroethane

Chloroform

Chloromethane

cis-1,2-Dichloroethene

cis-1,3-Dichloropropene

Dibromochloromethane

1,1-Dichloroethane

1,2-Dichloroethane

1,1-Dichloroethene

1,2-Dichloropropane

Ethyl benzene

Freon 113

2-Hexanone (MBK)

Methylene Chloride

4-Methyl-2-pentanone (MIBK)

Styrene

1,1,2,2-Tetrachloroethane

Tetrachloroethene

Tertiary butyl methyl ether

1,1,1-Trichloroethane

1,1,2-Trichloroethane

Toluene

trans-1,2-Dichloroethene

trans-1,3-Dichloropropene

Trichloroethene

Trichlorofluoromethane

Vinyl chloride

Xylene (ortho)

Xylene (total meta and para)

total meta and para)

Acetone

Allyl chloride

Benzene

Bromobenzene

Bromodichloromethane

Bromoform

Bromomethane

2-Butanone (MEK)

n-Butylbenzene

s-Butylbenzene

t-Butylbenzene

Carbon disulphide

Carbon tetrachloride

Chlorobenzene

1-Chlorobutane

Chloroethane

Chloroform

Chloromethane

2-Chlorotoluene

4-Chlorotoluene

Dibromochloromethane

1,2-Dibromoethane

1,2-Dibromo-3-chloropropane

Dibromomethane

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

trans-1,4-Dichloro-2-butene

Dichlordifluoromethane

1,1-Dichloroethane

1,2-Dichloroethane

1,1-Dichloroethene

2,2-Dichloropropane

cis-1,2-Dichloroethene

trans-1,2-Dichlorethene

1,2-Dichloropropane

1,3-Dichloropropane

1,1-Dichloropropene

cis-1,3-Dichloropropene

trans-1,3-Dichloropropene

Diethyl ether

Ethyl benzene

Ethyl methacrylate

Hexachlorobutadiene

Hexachloroethane

2-Hexanone (MBK)

Methylene chloride

Methyl methacrylate

4-Methyl-2-pentanone (MIBK)

Naphthalene

2-Nitropropane

Pentachloroethane

i-Propylbenzene

n-Propylbenzene

4-i-Propyltoluene

Styrene

Tertiary butyl methyl ether (TBME)

1,1,1,2-Tetrachloroethane

1,1,2,2-Tetrachloroethane

Tetrachloroethene

Tetrahydrofuran

Toluene

1,2,3-Trichlorobenzene

1,2,4-Trichlorobenzene

1,1,1-Trichloroethane

1,1,2-Trichloroethane

Trichloroethene

Trichlorofluoromethane

1,2,3-Trichloropropane

1,2,4-Trimethylbenzene

1,3,5-Trimethylbenzene

Vinyl chloride

Xylene (ortho)

Xylene (total meta and para)

Limit of Detection:
Waters: 0.8-20µg/L
Soils Low level: 0.8-20µg/Kg
Soils Medium level: 100-2500µg/Kg

Click here to see limits of detection for individual VOCs.


Sample required:
Waters: 40ml
Because of the potential for the loss of volatiles into the headspace above the sample, no headspace should be left when filling the sample bottle. Where a headspace is observed this should be considered when interpreting the data.
Soils: 30g

Containers:
Waters: clear glass vial/teflon septa
Soils: clear soda glass

Notes:
1. MDLs may be affected by sample matrix interferences, dilutions
2. If requested, the list of determinands may vary: call to confirm